Product ID:884 7972,PT A,KODAK EKTACHROME R-3 BLEACH (SEE SUPPL DATA)
MSDS Date:02/25/2000
FSC:6750
NIIN:01-201-9676
Status Code:A
Kit Part:Y
MSDS Number: CKWBQ

EASTMAN KODAK COMPANY

343 STATE STREET
ROCHESTER, NY 14650
US

Emergency Phone: 716 722-5151

Info Phone: 716-722-5151/(800) 242-2424

Preparer: NOT PROVIDED

Cage: 19139

EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS

ROCHESTER, NY 14650-1115 US

Telephone: 716-722-5151/(800) 242-2424

Cage: 19139

AMMONIUM THIOSULFATE

CAS: 7783-18-8

RTECS: XN6465000

OSHA PEL NOT PROVIDED

ACGIH TLV: NOT PROVIDED

WATER

CAS: 7732-18-5

RTECS: ZC0110000

SODIUM BISULFITE

CAS: 7631-90-5

RTECS: VZ2000000

OSHA PEL NOT PROVIDED

ACGIH TLV: 5 MG/M3

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

AMMONIUM ACETATE

CAS: 631-61-8

RTECS: AF3675000

OSHA PEL NOT PROVIDED

ACGIH TLV: NOT PROVIDED

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

AMMONIUM BISULFITE

CAS: 10192-30-0

RTECS: WT3595000

OSHA PEL NOT PROVIDED

ACGIH TLV: NOT PROVIDED

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:NOT PROVIDED
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EFFECTS OF EXPOSURE: INHALATION:
EXPECTED TO BE A LOW HAZARD FOR RECOMMENDED HANDLING. IN CONTACT
WITH STRONG ACIDS OR IF HEATED, SULFITES MAY LIBERATE SULFUR
DIOXIDE GAS. SULFUR DIOXIDE GAS IS IRRITA TING TO THE RESPIRATORY
TRACT. SOME ASTHMATICS OR HYPERSENSITIVE INDIVIDUALS MAY EXPERIENCE
DIFFICULT BREATHING. EYES: CAUSES IRRITATION. SKIN: THIS MATERIAL
HAS A LOW POTENTIAL TO CAUSE ALLERGIC SKIN REACTIONS; HOWEVER,
CASES OF HUMAN SKIN SENSITIZATION HAVE BEEN REPORTED. INGESTION:
MAY BE HARMFUL IF SWALLOWED. MAY CAUSE IRRITATION OF THE
GASTROINTESTINAL TRACT.
Explanation of Carcinogenicity:CARCINOGENICITY CLASSIFICATION
(COMPONENTS PRESENT AT 0.1% OR MORE):- INTERNATIONAL AGENCY FOR
RESEARCH ON CANCER (IARC): NONE - AMERICAN CONFERENCE OF
GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH):SODIU M BISULFITE; A4,
NOT CLASSIFIABLE AS A HUMAN CARCINOGEN. - NATIONAL TOXICOLOGY
PROGRAM (NTP): NONE - OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
(OSHA): NONE
Effects of Overexposure:INHALATION: IN CONTACT WITH STRONG ACIDS OR IF
HEATED, SULFITES MAY LIBERATE SULFUR DIOXIDE GAS. SULFUR DIOXIDE
GAS IS IRRITATING TO THE RESPIRATORY TRACT. SOME ASTHMATICS OR
HYPERSENSITIVE INDIVIDUAL S MAY EXPERIENCE DIFFICULT BREATHING.
EYES: CAUSES IRRITATION.
Medical Cond Aggravated by Exposure:SOME ASTHMATICS, HYPERSENSITIVE OR
SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING,
WHEEZING, CHEST TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS,
WEAKNESS AND DIARRHEA.

First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. TREAT
SYMPTOMATICALLY. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES:
IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET
MEDICAL ATTEN TION IF SYMPTOMS OCCUR. SKIN: WASH WITH SOAP AND
WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. INGESTION: DRINK
1-2 GLASSES OF WATER. SEEK MEDICAL ATTENTION. NEVER GIVE ANYTHING
BY MOUTH TO AN UNCO NSCIOUS PERSON.

Flash Point:NONE
Extinguishing Media:FLOOD WITH WATER.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:SOLUTION CONTAINS A STRONG REDUCING
AGENT. DRIED PRODUCT RESIDUE CAN ACT AS A REDUCING AGENT.

Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER.
OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL,
THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
Neutralizing Agent:NOT PROVIDED

Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED TO
PREVENT THE LOSS OF WATER. KEEP AWAY FROM INCOMPATIBLE SUBSTANCES.
DO NOT STORE OR SHIP TOGETHER WITH COMBUSTIBLE MATERIALS. STORE IN
ORIGINAL CONTAINER. KEEP AWAY FRO M COMBUSTIBLE MATERIAL. REMOVE
AND WASH CONTAMINATED CLOTHING. WASH THOROUGHLY AFTER HANDLING.
Other Precautions:AVOID BREATHING MIST OR VAPOR. AVOID CONTACT WITH
EYES AND PROLONGED OR REPEATED CONTACT WITH SKIN. USE WITH ADEQUATE
VENTILATION. KEEP FROM CONTACT WITH OXIDIZING MATERIALS, HIGHLY
OXYGENATED OR HALO GENATED SOLVENTS, ORGANIC COMPOUNDS CONTAINING
REDUCIBLE FUNCTIONAL GROUPS, OR AQUEOUS AMMONIA.

Respiratory Protection:A RESPIRATOR SHOULD BE WORN IF HAZARDOUS
DECOMPOSITION PRODUCTS ARE LIKELY TO BE OR HAVE BEEN RELEASED.
RESPIRATOR TYPE: ACID GAS. SEE STABILITY AND REACTIVITY SECTION. IF
RESPIRATORS ARE USED, A PRO GRAM SHOULD BE INSTITUTED TO ASSURE
COMPLIANCE WITH OSHA STANDARD 29 CFR 1910.134.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER
HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO
CONDITIONS.
Protective Gloves:FOR PROLONGED OR REPEATED SKIN CONTACT: IMPERVIOUS
GLOVES SHOULD BE WORN.
Eye Protection:WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
Other Protective Equipment:EYE BATH, SAFETY SHOWER, WASHING FACILITIES.
Work Hygienic Practices:IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO
MINIMIZE EYE CONTACT. IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO
MINIMIZE SKIN CONTACT.
Supplemental Safety and Health
CONTINUED FROM PRODUCT ID: FIX II AND REPLENISHER. ABBREVIATION:
N/A=NOT APPLICABLE OR NOT AVAILABLE. N/K=UNKNOWN. N/P=NOT PROVIDED.
N/R=NOT RELEVANT. N/D=NOT DETERMINED. N/E=NOT ESTABLISHED.

HCC:N1
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:>100.C, 212.F
Melt/Freeze Pt:M.P/F.P Text:NOT PROVIDED
Decomp Temp:Decomp Text:NOT PROVIDED
Vapor Pres:(68F):24 MBAR (18 MM HG)
Vapor Density:0.6
Spec Gravity:1.33
pH:5.3
Viscosity:NOT PROVIDED
Evaporation Rate & Reference:NOT PROVIDED
Solubility in Water:COMPLETE
Appearance and Odor:COLORLESS LIQUID. ODOR: AMMONIA.
Percent Volatiles by Volume:40-45 WT
Corrosion Rate:NOT PROVIDED

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, BASES, STRONG OXIDIZING AGENTS, SODIUM HYPOCHLORITE
(BLEACH), COMBUSTIBLE MATERIAL, HALOGENATED MATERIALS. CONTACT WITH
BASE LIBERATES FLAMMABLE MATERIAL.
Stability Condition to Avoid:NOT PROVIDED
Hazardous Decomposition Products:AMMONIA, CHLORAMINE, SULFUR DIOXIDE,
OXIDES OF NITROGEN, OXIDES OF SULFUR.

Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE AMOUNT
OF WATER. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE, FOLLOW
LABEL WARNINGS EV EN AFTER CONTAINER IS EMPTIED.

Toxicological Information:EFFECTS OF EXPOSURE: INHALATION: EXPECTED TO
BE A LOW HAZARD FOR RECOMMENDED HANDLING. IN CONTACT WITH STRONG
ACIDS OR IF HEATED, SULFITES MAY LIBERATE SULFUR DIOXIDE GAS.
SULFUR DIOXIDE GAS IS IRRITA TING TO THE RESPIRATORY TRACT. SOME
ASTHMATICS OR HYPERSENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT
BREATHING. EYES: CAUSES IRRITATION. SKIN: THIS MATERIAL HAS A LOW
POTENTIAL TO CAUSE ALLERGIC SKIN REACTIONS; HOWEVER, CASES OF
HUMAN SKIN SENSITIZATION HAVE BEEN REPORTED. INGESTION: MAY BE
HARMFUL IF SWALLOWED. MAY CAUSE IRRITATION OF THE GASTROINTESTINAL
TRACT.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:THE FOLLOWING PROPERTIES ARE ESTIMATED FROM THE COMPONENTS
OF THE PREPARATIONS. POTENTIAL TOXICITY: FISH LC50 MG/L: >100.
DAPHNID EC50 MG/L: >100. ALGAL IC50 MG/L: >100. ORGANICS
READILY DEGRAD ABLE (>70%): YES (7 DAYS). POTENTIAL
BIOACCUMULATION: LOG POW <1. COD (APPROXIMATE G/L): 335. BOD5
(APPROXIMATE G/L): 270. POTENTIAL TOXICITY: WASTE TREATMENT
MICROORGANISMS EC50 (MG/L): >100.

Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS
PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE:
(716) 722-2400 BETWEEN 8 A.M. AND 5 P.M. (EASTERN STANDARD TIME),
MONDAY THROUGH FRIDAY .

SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR
PART 372: AMMONIUM THIOSULFATE, AMMONI UM BISULFITE, AMMONIUM
ACETATE, AS A SOURCE OF AQUEOUS AMMONIA.
Federal Regulatory Information:NOT PROVIDED
State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER: NONE - MATERIAL(S) KNOWN TO THE STATE
OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE